Lots of genres, not repeating any Band (except Therion, but with 3 different styles). You cannot go wrong with this list, some nice Starts to any kind of Metal.
The list is sorted by year, but has not any particular order. Enjoy!
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Queensrÿche - Operation: Mindcrime|
Atheist - Unquestionable Presence|
Therion - Symphony Masses - Ho Drakon Ho Megas|
Cynic - Focus|
Amorphis - Tales From The Thousand Lakes|